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晶体的X射线衍射理论——劳厄与埃瓦尔德的遗产

Theory of X-ray diffraction in crystals——the legacy of Laue and Ewald

  • 摘要: 文章概述了晶体X射线衍射理论的发展过程,介绍了不同形式的衍射几何理论、劳厄方程、布拉格方程与埃瓦尔德作图法,讨论了它们之间的异同之处.文章还介绍了运动学衍射理论和不同形式的动力学衍射理论,后者包括达尔文的简化处理、埃瓦尔德的表述和劳厄的表述,并对其物理后果进行了讨论,强调了动力学理论所预言的电磁波在周期结构中传播所引起的能隙.

     

    Abstract: A brief survey of the theory of X-ray diffraction in crystals is given. Different forms of geometrical diffraction theory, i.e., the Laue equation, Bragg equation and Ewald diagram are introduced and their similarities and differences discussed. The kinematical diffraction theory and different forms of dynamical diffraction theory, i.e., Darwin′s simplified treatment, Ewald′s formulation and Laue's formulation, as well as their physical consequences are discussed, emphasis is put on the energy gap, predicted by dynamical diffraction theory, created by the propagation of electromagnetic waves in periodic structures.

     

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